Rabu, 10 Mei 2017

stoichiometry


        Using a balanced chemical equation to calculate amounts of reactants and products is called stoichiometry. It is a super technical-sounding word that simply means using ratios from the balanced equation. In this article, we will discuss how to use mole ratios to calculate the amount of reactants needed for a reaction.

  The Mole      
       Given the equation above, we can tell the number of moles of reactants and products. A mole simply represents Avogadro's number (6.022 x 1023) of molecules. A mole is similar to a term like a dozen. If you have a dozen carrots, you have twelve of them. Similarly, if you have a mole of carrots, you have 6.022 x 1023 carrots. In the equation above there are no numbers in front of the terms, so each coefficient is assumed to be one (1). Thus, you have the same number of moles of AgNO3, NaCl, AgCl, NaNO3.
        Converting between moles and grams of a substance is often important. This conversion can be easily done when the atomic and/or molecular mass of the substance(s) are known. Given the atomic or molecular mass of a substance, that mass in grams makes a mole of the substance. For example, calcium has an atomic mass of 40 atomic mass units. So, 40 grams of calcium makes one mole, 80 grams makes two moles, etc.
      Describing the quantitative relationships among substances as they participate in chemical reactions is known asreaction stoichiometry. In the example above, reaction stoichiometry measures the relationship between the methane and oxygen as they react to form carbon dioxide and water.
Atomic Mass
1. relative atomic mass (Ar)
Measuring the mass is comparing the mass of an object to another, in which the mass of the reference object is called the standard mass.
2. Relative Molecular Mass and Mass Relative Formula (Mr)
The mass of a molecule of a compound is called the relative molecular mass (Mr). The magnitude of the relative molecular mass of a compound is the sum of the relative atomic mass (Ar) of its constituent elements.
Mr AxBy = (x  Ar A + y Ar B)
3. Average atomic mass
Atoms of the same element do not always have the same mass. This is known as isotopes. The atoms in nature can have different masses, then the atomic mass is calculated on the average mass of all the atoms in nature.
Molar proportion
Stoichiometry is often used to balance chemical equations (reaction stoichiometry). For example, the two diatomic gases, hydrogen and oxygen, can combine to form a liquid, water, in an exothermic reaction, as described by the following equation:
H
2
+ O
2
→ 2 H
2
O
Reaction stoichiometry describes the 2:1:2 ratio of hydrogen, oxygen, and water molecules in the above equation.
The molar ratio allows for conversion between moles of one substance and moles of another. For example, in the reaction
CH
3
OH
+ 3 O
2
→ 2 CO
2
+ 4 H
2
O
the amount of water that will be produced by the combustion of 0.27 moles of CH
3
OH
is obtained using the molar ratio between CH
3
OH
and H
2
O
of 2 to 4.
The term stoichiometry is also often used for the molar proportions of elements in stoichiometric compounds (composition stoichiometry). For example, the stoichiometry of hydrogen and oxygen in H2O is 2:1. In stoichiometric compounds, the molar proportions are whole numbers.


18 komentar:

  1. What is the benefit of studying stoichiometry in daily life?

    BalasHapus
    Balasan
    1. The principles of stoichiometry can be used while cooking.
      If you were almost out of a specific ingredient, you could use the principles of stoichiometry to figure out how much of every other ingredient you would need (treating the ingredient you were almost out of as the "limiting reagent").
      Stoichiometry continues to be useful in many walks of life—a farmer determining how much fertilizer to use, figuring out how fast you have to go to get somewhere in a specific period of time, or just to make conversions between systems like Celsius and Fahrenheit.

      Hapus
  2. Is stoichiometry only used in chemistry only?

    BalasHapus
    Balasan
    1. Yes, because Stoichiometry is a subject in chemistry involving the linkage of reactants and products in a chemical reaction to determine the quantity of each reacting agent.

      Hapus
  3. Can you give me an example of stoichiometry other than in chemistry?

    BalasHapus
    Balasan
    1. Stoichiometry is a science that studies and quantifies quantitative relationships of reactants and products in chemical reactions (chemical equations). So I can not give stoichiometric examples other than in chemistry to you.

      Hapus
  4. Is there any other material about stoichiometry other than what you have described in your blog? If any please explain some other.

    BalasHapus
    Balasan
    1. yes these are about relationship with law in the stoichiometry. there are The Law of Conservation of Mass
      LAW MASS LAW = LAVOISIER LAW
      "The mass of substances before and after the reaction is fixed".
      Example:
      Hydrogen + oxygen of hydrogen oxide
      (4g) (32g) (36g)


      D. Comparable Law (Proust Law)
      Fixed Comparison Law: The chemical compound consists of chemical elements with the ratio of the mass of elements that remain the same.
      PERSONAL COMPARATIVE LAW = PROUST LEGAL
      "The ratio of the mass of the elements in each compound is fixed"
      The Law of Multiple Comparisons (Dalton's Law)
      The Law of Multiple Comparisons: If an element reacts with other elements, then the ratio of the weight of the element is a simple integer
      So from persmaaan:
      2Na (s) + 2HCl (aq) → 2NaCl (aq) + H2 (g)
      LEGAL COMPARATIVE LAW = LEGAL DALTON
      "If two elements can form two or more compounds for the mass of one element equal to the number then the ratio of the mass of the second element will be proportional to the integer and the simple".

      Hapus
  5. Avogadro number is 6,02 x 10^23 right? Why?

    BalasHapus
    Balasan
    1. Because that number is a prescribed determination

      Hapus
  6. Can you explain about history of stoichiometry ?

    BalasHapus
    Balasan
    1. The word stoichiometry derives from two Greek words: stoicheion (meaning "element") and metron (meaning "measure"). Stoichiometry deals with calculations about the masses (sometimes volumes) of reactants and products involved in a chemical reaction.

      It is a very mathematical part of chemistry, so be prepared for lots of calculator use.

      Jeremias Benjaim Richter (1762-1807) was the first to lay down the principles of stoichiometry.

      In 1792 he wrote:

      "Die stöchyometrie (Stöchyometria) ist die Wissenschaft die quantitativen oder Massenverhältnisse zu messen, in welchen die chymischen Elemente gegen einander stehen." [Stoichiometry is the science of measuring the quantitative proportions or mass ratios in which chemical elements stand to one another.

      Hapus
  7. What is the difference between the volume in normal circumstances with the volume in the STP state?

    BalasHapus
    Balasan
    1. for the volume in normal circumstances is Depending on the solution used, including the mixture
      for the volume in the STP state is the abbreviation for Standard Temperature and Pressure. STP most commonly is used when performing calculations on gases, such as gas density. The standard temperature is 273 K (0° Celsius or 32° Fahrenheit) and the standard pressure is 1 atm pressure. This is the freezing point of pure water at sea level atmospheric pressure. At STP, one mole of gas occupies 22.4 L of volume (molar volume).

      Hapus
  8. Please you mention the fixed comparison law.

    BalasHapus
    Balasan
    1. A. The Law of Conservation of Mass (Lavoisier's Law)
      "The mass of substances before and after the reaction is the same".
      Example:
      S + O 2 → SO 2
      2 gr 32 gr 64 gr

      B. Fixed Comparative Law (Proust Law)
      "The ratio of the elemental masses in each compound is fixed"
      Example:
      H 2 O → mass H: mass O = 2: 16 = 1: 8

      C. The Law of Multiple Comparisons (Dalton's Law)
      "If two elements can form two or more compounds, and the mass of one element is equal, the ratio of the mass of the second element is proportional to the simple and integer".

      Hapus
  9. how to find everage atomic mass?

    BalasHapus
  10. Average atomic mass is not a direct measurement of a single atom. Instead, it is the average mass per atom for a typical sample of a given element. If you could measure the mass of billions of individual atoms, you could calculate this value the same way you would find any average. Fortunately, there is a more practical method that relies on recorded information on the rarity of different isotopes.

    BalasHapus

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